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Noiva, R

Ramaekers VT, et al

In kainic acid (KA)-treated rats, TIGAR upregulation in cortex and hippocampus was accompanied by increased ROS levels, decreased antioxidant indices and increased pro-apoptotic factors

These enzymes can deploy Ni 2+ as a Lewis acid (electrophilic center), as seen in urease and glyoxalase I, or use redox chemistry as seen in NiSOD, Ni-Fe hydrogenase and CO dehydrogenase (Maroney & Ciurli, 2014)